fsck all partitions, be sure to check lvm partitions.
Boot into CentOS 6.5 rescue mode to reinstall grub (MBR)
Choose to mount under /mnt/sysimage
chroot /mnt/sysimage
grub-install /dev/sda
If you get this problem: /dev/sdb1 does not have any corresponding BIOS drive, edit the /boot/grub/device.map temporary to point to /dev/sdb. Reinstall grub and change back the device.map file.